You can already add friends, not quite sure when you can purchase items tho, you can probably purchase items now, but wont be able to trade it or gift it until 7 days.
You need atleast to purchase 1 item in order to add friends. Assuming your playing a lot of games, a 1 month dota plus is the best first item to buy. Shards can buy you a lot of hero sets.
I think you need 30 days before you can buy/sell in the community market.
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so recently I got my 250php Steam wallet, can I add friend already and when can I buy Items? I got authenticator already. TY